Product ID:B&B 120S
MSDS Date:07/18/1986
FSC:6850
NIIN:00N030697
MSDS Number: BNMKB

B & B CHEMICAL CO INC

875 WEST 20TH STREET
HIALEAH, FL 33010
US

Emergency Phone: 305-888-5247

Info Phone: 305-888-5247

Cage: EO030

B & B TRITECH, INC.

HIALEAH, FL 33010-2310 US

Telephone: 305-888-5247

Cage: 21361

OF 1,5000PPM & ABOVE. RATS EXPOS TO

RTECS: 9999999ZZ

MICE & RATS EXPOS BY INGEST @ LEVELS OF 250 MG/KG/DAY

RTECS: 9999999ZZ

3,500PPM LIFETIME DO NOT SHOW AN INCR INCIDENCE OF

RTECS: 9999999ZZ

CONSIDERS LIVER & LUNG TUMORS IN MICE AS LIM EVIDENCE

RTECS: 9999999ZZ

MAMMARY GLAND TUMORS IS UNKNOWN. EPIDEMIOLOGY STUDIES

RTECS: 9999999ZZ

CHLORIDE IN WORKPLACE FOR MINIMUM OF 20 YRS DID NOT

RTECS: 9999999ZZ

CARDIAC PROBLEMS. SECOND STUDY OF 2,227 WORKERS

RTECS: 9999999ZZ

CONDUCTED TO EVALUATE ADVERSE EFTS METHYLENE

RTECS: 9999999ZZ

THE RSLTS INDICATE THAT METHYLENE CHLORIDE DOES NOT

RTECS: 9999999ZZ

MATL HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE

RTECS: 9999999ZZ

ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE

RTECS: 9999999ZZ

ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .

RTECS: 9999999ZZ

METHANE, DICHLORO-; (METHYLENE CHLORIDE)

CAS: 75-09-2

RTECS: PA8050000

OSHA PEL 500 PPM;1000, C

ACGIH TLV: 50 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PHENOL

CAS: 108-95-2

RTECS: SJ3325000

OSHA PEL 5 PPM, SKIN

ACGIH TLV: 5 PPM, SKIN

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CRESOL

CAS: 1319-77-3

RTECS: GO5950000

OSHA PEL 5 PPM, SKIN

ACGIH TLV: 5 PPM, SKIN

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:DIZZ/HDCH/NAUS MAY OCCUR IF VENT IS
INADEQ. SKIN: INITIAL CONT PRDCES WHITE WRINKLED DISCOLORATION
YIELDING SERIOUS BURN OR SYSTEMATIC POISONING IF NOT REMOVE
PROMPTLY. EYES: BURNS, EYE DAM. DIZZ/HDCH /NAUS, SEV BURNING TO
SKIN & EYES. METHYLENE CHLORIDE HAS BEEN EVALUATED FOR POSS CANCER
CAUSING EFTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: GROUP 2B (IARC),
ANTICIPATED T BE A CARCINOGEN. (NTP).
Effects of Overexposure:HLTH HAZ: IN LAB ANIMALS. INHAL STUDIES @ CONC
OF 1,000, 2,000, & 4,00O PPM INCR INCIDENCE OF MALIGNANT LIVER &
LUNG TUMORS IN MICE. 3 INHAL STUDIES OF RATS HAVE SHOWN INCR
INCIDENCE OF BENIGN MAMMARY GLAND TUMORS IN FEMALE RATS @ CONC OF
500PPM & ABOVE & INCR IN BENIGN MAMMARY GLAND TUMORS IN MALES @
CONC (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INGEST: DO NOT INDUCE VOMIT. GET MD. SKIN: FLUSH WITH WATER.
GET MD. EYE: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MIN. GET
MD. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRAT ION.

Flash Point Method:COC
Flash Point:NONE TO BOIL
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC & ACIDIC VAPORS. THERMAL
DECOMPOSITION PRODUCTS MAY INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:ABSORB WITH SAND OR INERT MATERIAL. INDUSTRIAL
VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTD AREA.
KEEP DRUMS CLSD WHEN NOT IN USE. AVOID CONT W/SKIN/EYES/CLTHG.
AVOID BRTHG VAP.
Other Precautions:WHEN B&B 120S IS USED IN A CLEANING-STRIP TANK FOR
WORK PROFCESSING IT IS RECOM THAT @ LST A 4 IN CHEM SEAL BE ADDED
TO TANK TO AVOID EVAP OF ACTIVE MATL, IF USER ADDS CHEM SEAL TO B&B
120S USER MUST INVESTIGATE TO DETERM (SUPP DATA)

Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC VAPOR.
Ventilation:DO NOT USE IN CLSD/CONFINED SPACES. OPEN DOORS/WINDOWS. USE
VENT TO MAINTAIN EXPOSURE LEVELS BELOW 100 PPM.
Protective Gloves:CHEMICAL GLOVES.
Eye Protection:CHEM WORK GOG & FULL LENGTH FSHLD.
Other Protective Equipment:FULL CHEMICAL/ACID SUIT; CHEM BOOTS; APRON.
EQUIP MAY VARY WITH ACTUAL USAGE. EMERGENCY EYE WASH & DELUGE
SHOWER
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HMIS(LEVIEN) HAS ASSIGNED HCC OF T3 DUE TO THE PRESENCE OF PHENOL,WHICH
IS CLASS 6.1,GRP II(NOTE:MFR DOES NOT SPECIFY PERCENTAGE).NO
SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC WELD, OPEN F
LAMES & HOT SURF. HEAT &/OR UV RADIA MAY CAUSE FORM OF HCL &/OR
PHOSGENE .

HCC:T3
Boiling Pt:B.P. Text:100F,38C
Spec Gravity:1.22(H2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:LIQUID-CHLORINATED SOLVENT ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE (SMALL
AMOUNT).

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.